Posts Tagged 'globalmodeling'

Timing of global regression and microbial bloom linked with the Permian-Triassic boundary mass extinction: implications for driving mechanisms

New high-resolution U-Pb dates indicate a duration of 89 ± 38 kyr for the Permian hiatus and of 14 ± 57 kyr for the overlying Triassic microbial limestone in shallow water settings of the Nanpanjiang Basin, South China. The age and duration of the hiatus coincides with the Permian-Triassic boundary (PTB) and the extinction interval in the Meishan Global Stratotype Section and Point, and strongly supports a glacio-eustatic regression, which best explains the genesis of the worldwide hiatus straddling the PTB in shallow water records. In adjacent deep marine troughs, rates of sediment accumulation display a six-fold decrease across the PTB compatible with a dryer and cooler climate as indicated by terrestrial plants. Our model of the Permian-Triassic boundary mass extinction (PTBME) hinges on the synchronicity of the hiatus with the onset of the Siberian Traps volcanism. This early eruptive phase released sulfur-rich volatiles into the stratosphere, thus simultaneously eliciting a short-lived ice age responsible for the global regression and a brief but intense acidification. Abrupt cooling, shrunk habitats on shelves and acidification may all have synergistically triggered the PTBME. Subsequently, the build-up of volcanic CO2 induced a transient cool climate whose early phase saw the deposition of the microbial limestone.

Continue reading ‘Timing of global regression and microbial bloom linked with the Permian-Triassic boundary mass extinction: implications for driving mechanisms’

The geologic history of seawater pH

Although pH is a fundamental property of Earth’s oceans, critical to our understanding of seawater biogeochemistry, its long-timescale geologic history is poorly constrained. We constrain seawater pH through time by accounting for the cycles of the major components of seawater. We infer an increase from early Archean pH values between ~6.5 and 7.0 and Phanerozoic values between ~7.5 and 9.0, which was caused by a gradual decrease in atmospheric pCO2 in response to solar brightening, alongside a decrease in hydrothermal exchange between seawater and the ocean crust. A lower pH in Earth’s early oceans likely affected the kinetics of chemical reactions associated with the origin of life, the energetics of early metabolisms, and climate through the partitioning of CO2 between the oceans and atmosphere.

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Rapid emergence of climate change in environmental drivers of marine ecosystems

Climate change is expected to modify ecological responses in the ocean, with the potential for important effects on the ecosystem services provided to humankind. Here we address the question of how rapidly multiple drivers of marine ecosystem change develop in the future ocean. By analysing an ensemble of models we find that, within the next 15 years, the climate change-driven trends in multiple ecosystem drivers emerge from the background of natural variability in 55% of the ocean and propagate rapidly to encompass 86% of the ocean by 2050 under a ‘business-as-usual’ scenario. However, we also demonstrate that the exposure of marine ecosystems to climate change-induced stress can be drastically reduced via climate mitigation measures; with mitigation, the proportion of ocean susceptible to multiple drivers within the next 15 years is reduced to 34%. Mitigation slows the pace at which multiple drivers emerge, allowing an additional 20 years for adaptation in marine ecological and socio-economic systems alike.

Continue reading ‘Rapid emergence of climate change in environmental drivers of marine ecosystems’

Amplification of global warming through pH-dependence of DMS-production simulated with a fully coupled Earth system model

We estimate the additional transient surface warming ΔTs caused by a potential reduction of marine dimethyl sulfide (DMS) production due to ocean-acidification under the high emission scenario RCP8.5 until the year 2200. Since we use a fully coupled Earth system model, our results include a range of feedbacks, such as the response of marine DMS-production to the additional changes in temperature and sea-ice cover. Our results are broadly consistent with the findings of a previous study that employed an off-line model set-up. Assuming a medium (strong) sensitivity of DMS-production to pH, we find an additional transient global warming of 0.30 K (0.47 K) towards the end of the 22nd century when DMS-emission are reduced by 7.3 Tg S yr−1 or 31 % (11.5 Tg S yr−1 or 48 %). The main mechanism behind the additional warming is a reduction of cloud albedo, but a change in short-wave radiative fluxes under clear-sky conditions due to reduced sulfate aerosol load also contributes significantly. We find an approximately linear relationship between reduction of DMS-emissions and changes in top of the atmosphere radiative fluxes as well as changes in surface temperature for the range of DMS-emissions considered here. For example, global average Ts changes by −0.041 K per 1 Tg S yr−1 change in sea-air DMS-fluxes. The additional warming in our model has a pronounced asymmetry between northern and southern high latitudes. It is largest over the Antarctic continent, where the additional temperature increase of 0.56 K (0.89 K) is almost twice the global average. We find that feedbacks are small on the global scale due to opposing regional contributions. The most pronounced feedback is found for the Southern Ocean, where we estimate that the additional climate change enhances sea-air DMS-fluxes by about 9 % (15 %), which counteracts the reduction due to ocean acidification.

Continue reading ‘Amplification of global warming through pH-dependence of DMS-production simulated with a fully coupled Earth system model’

Risk and resilience: variations in magnesium in echinoid skeletal calcite

Echinoids have high-magnesium (Mg) calcite endoskeletons that may be vulnerable to CO2-driven ocean acidification. Amalgamated data for echinoid species from a range of environments and life-history stages allowed characterization of the factors controlling Mg content in their skeletons. Published measurements of Mg in calcite (N = 261), supplemented by new X-ray diffractometry data (N = 382), produced a database including 8 orders, 23 families and 73 species (~7% of the ~1000 known extant species), spanning latitudes 77°S to 72°N, and including 9 skeletal elements or life stages. Mean (± SD) skeletal carbonate mineralogy in the Echinoidea is 7.5 ± 3.23 wt% MgCO3 in calcite (range: 1.5-16.4 wt%, N = 643). Variation in Mg within individuals was small (SD = 0.4-0.9 wt% MgCO3). We found significant differences among skeletal elements: jaw demi-pyramids were the highest in Mg, whereas tests, teeth and spines were intermediate in Mg, but generally higher than larvae. Higher taxa have consistent mineralogical patterns, with orders in particular showing Mg related to first appearance in the fossil record. Latitude was a good proxy for sea-surface temperature (SST), although incorporating SST where available produced a slightly better model. Mg content varied with latitude; higher Mg content in warmer waters may reflect increased metabolic and growth rates. Although the skeletons of some adult urchins may be partially resistant to ocean acidification, larvae and some species may prove to be vulnerable to lowered pH, resulting in ecosystem changes in coastal marine environments.

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Earth 2075—CO2 II. Targeting 0°C Global Warming, Ocean pH 8.2, and an Early Return to 280 ppm

In this second paper of CRT’s EARTH 2075—CO2 series, revised emissions targets take into account fossil fuel combustion and cement production trends, global change inertia, and developing countries’ future energy needs. Global CO2 emissions are currently ~10 GtC/yr. A 12 GtC/yr cap is recommended by 2023. A realistic schedule for subsequently reducing emissions is recommended—returning to 10.5 GtC/yr by 2030 and cutting to 6 GtC/yr by 2050, 3 GtC/yr by 2062, and 1 GtC/yr by 2078. Our forecasting model assumes developing countries (DC) would moderately burn fossil fuels through 2062 while today’s industrial nations compensate with high-impact atmospheric carbon capture, plus offsetting emissions reductions of their own—sufficient to cap global emissions by 2023 and enable the above-targeted reductions through 2062. Developing countries would begin or accelerate their emissions cuts in 2063. Our forecasting model projects emissions cap and reduction impact on the accumulated mixing ratio (ppm) for atmospheric CO2. Emissions cuts alone are no longer likely to prevent CO2 from reaching 450 ppm tipping levels. More drastic emergency intervention is required to forestall tipping level crossings and prevent disastrous future consequences, including ≥ 2°C warming accompanied by mega-drought, superstorms, partial polar ice collapse, and abrupt catastrophic sea rise. A new approach involving massively amplified safe capture of atmospheric CO2 at sea is proposed. This paper establishes open-ocean amplified capture targets and forecasts the beneficial impacts of meeting them. Recommended high impact targets for mid-ocean capture and sequestration of atmospheric CO2 include contingency for delays and energy to drive multi-stage (land/sea) amplified capture plus extra contingency to offset feedbacks, outgassing, and permafrost thaw-release, which the model didn’t anticipate. CRT recommends starting multi-stage short-cycle ocean-amplified carbon capture (OACC) in 2019 and ramping it up to net 10 GtC/yr average CO2 capture by 2025 across vast mid-latitude, mid-ocean expanses—far out at sea and well away from coastal waters—plus simultaneously compounding benefits of the 12 GtC/yr 2023 emissions cap and above-targeted post-2023 emissions reductions, culminating in 92 percent reduction by 2078. With the sum of OACC plus natural sinks matching capped emissions by 2023 and substantially exceeding reduced post-2023 emissions, accumulated atmospheric CO2 may be capped at ≤ 425 ppm by 2023 and reduced to 350 ppm by 2050, with an option to restore 280 ppm by 2075 and reduce twenty-first century warming to 0°C. High-impact ocean-amplified carbon capture (OACC) at the rate of 10 GtC/yr could enable DC emissions leniency and still turn 280 ppm atmospheric CO2, ∆T = 0°C, and ocean pH 8.2 into viable twenty-first century targets that can be met approximately 250 years earlier than with emissions reduction alone—if tropospheric aerosol pollution is concurrently reduced.

Continue reading ‘Earth 2075—CO2 II. Targeting 0°C Global Warming, Ocean pH 8.2, and an Early Return to 280 ppm’

An abyssal carbonate compensation depth overshoot in the aftermath of the Palaeocene–Eocene Thermal Maximum

During the Palaeocene–Eocene Thermal Maximum (PETM) about 56 million years ago, thousands of petagrams of carbon were released into the atmosphere and ocean in just a few thousand years, followed by gradual sequestration over approximately 200,000 years. If silicate weathering is one of the key negative feedbacks that removed this carbon, a period of seawater calcium carbonate saturation greater than pre-event levels would be expected during the event’s recovery phase. In marine sediments, this should be recorded as a temporary deepening of the depth below which no calcite is preserved — the calcite compensation depth (CCD). Previous and new sedimentary records from sites that were above the pre-PETM CCD show enhanced carbonate accumulation following the PETM. A new record from an abyssal site in the North Atlantic that lay below the pre-PETM CCD shows a period of carbonate preservation beginning about 70,000 years after the onset of the PETM, providing the first direct evidence for an over-deepening of the CCD. This record confirms an overshoot in ocean carbonate saturation during the PETM recovery. Simulations with two earth system models support scenarios for the PETM that involve a large initial carbon release followed by prolonged low-level emissions, consistent with the timing of CCD deepening in our record. Our findings indicate that sequestration of these carbon emissions was most likely the result of both globally enhanced calcite burial above the CCD and, at least in the North Atlantic, an over-deepening of the CCD.

Continue reading ‘An abyssal carbonate compensation depth overshoot in the aftermath of the Palaeocene–Eocene Thermal Maximum’


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