Ocean Acidification

Highlights

• The SST controls the seasonal and spatial variation of CO₂ fugacity and fluxes.

• The pH and fCO₂ shows spatial variability associated with upwelling influence.

• NC_T variation was mainly governed by biological activity and slightly affected by air-sea fluxes.

• During 2019, the Northeast Atlantic region behaved as an annual CO₂ sink of -2.65 ± 0.44 Tg CO₂ yr^-1

• VOS lines are a powerful tool to study de CO₂ system and fluxes in the coastal surface area.

Abstract

The seasonal and spatial variability of the CO₂ system parameters and CO₂ air-sea exchange were studied in the Northeast Atlantic Ocean between the northwest African coastal upwelling and the oligotrophic open-ocean waters of the North Atlantic subtropical gyre. Data was collected aboard a volunteer observing ship from February 2019 to February 2020. The seasonal and spatial variability of CO₂ fugacity in seawater (fCO_2,sw) was strongly driven by the seasonal temperature variation, which increased with latitude and was lower throughout the year in coastal regions where the upwelling and offshore transport was more intense. The thermal to biological effect ratio (T/B) was approximately 2, with minimum values along the African coastline related to higher biological activity in the upwelled waters. The fCO_2,sw increased from winter to summer by 11.84 ± 0.28 μatm°C^-1 on the inter-island routes and by 11.71 ± 0.25 μatm°C^-1 along the northwest African continental shelf. The seasonality of total inorganic carbon normalized to constant salinity of 36.7 (NC_T) was studied throughout the region. The effect of biological processes and calcification/dissolution on NC_T between February and October represented >90% of the reduction of inorganic carbon while air-sea exchange described <6%. The seasonality of air-sea CO₂ exchange was controlled by temperature. The surface waters of the entire region acted as a CO₂ sink during the cold months and as a CO₂ source during the warm months. The Canary basin acted as a net sink of -0.26 ± 0.04 molC m^-2 yr^-1. The northwest African continental shelf behaved as a stronger sink at -0.48 ± 0.09 molC m^-2 yr^-1. The calculated average CO₂ flux for the entire area was -2.65 ± 0.44 TgCO₂ yr^-1 (-0.72 ± 0.12 TgC yr^-1).

Curbelo-Hernández D., González-Dávila M., González A. G., González-Santana D. & Santana-Casiano J. M., in press. CO2 fluxes in the Northeast Atlantic Ocean based on measurements from a surface ocean observation platform. Science of The Total Environment. Article (subscription required).